毕业论文

打赏
当前位置: 毕业论文 > 化学论文 >

Fe0类Fenton技术氧化降解金橙I

时间:2020-10-16 15:39来源:毕业论文
选取难降解的偶氮染料金橙I作为目标物,采用Fe0类Fenton技术对其展开降解研究。实验结果表明0.6g/L的金橙I溶液在pH4.0、H2O2浓度为9mmol/L、零价铁粉投加量为0.4g/L的条件下能够被有效降解

摘要:Fe0类Fenton技术是一种新型高效的类Fenton技术,其利用Fe0的腐蚀产生Fe2+,然后Fe2+催化H2O2分解产生氧化性极强的·OH,进而氧化降解有机污染物。本论文中选取难降解的偶氮染料金橙I作为目标物,采用Fe0类Fenton技术对其展开降解研究。实验结果表明0.6g/L的金橙I溶液在pH4.0、H2O2浓度为9mmol/L、零价铁粉投加量为0.4g/L的条件下能够被有效降解。此外利用紫外可见分光光度计和pH计对每个时间段反应溶液中铁离子浓度、pH值及金橙I分别进行了分析测定和紫外可见光谱扫描,利用LC-MS对中间产物进行了分析测定,推测在氧化降解的过程中金橙I首先解离为4-羟基萘偶氮对苯磺酸根,然后其生色基团被氧化破坏,反应溶液褪色,生成苯磺酸根、氮气和1,4-萘醌,然后1,4-萘醌进一步氧化为邻苯二甲酸根。58106

毕业论文关键词:零价铁;有机污染物;氧化;降解率;金橙I

Degradation of Orange I by Fe0- Fenton

Abstract:Fe0-Fenton technology is a new type of high efficient Fenton-like technology, which uses the corrosion of Fe0 to produce Fe2+, and then Fe2+ catalytic decomposition of H2O2 to produce highly oxidized ·OH, and then ·OH oxidation degradation of organic pollutants. In this paper, the refractory azo dyes Orange I was selected as the target, and the Fe0-Fenton technology was used to study the degradation of Orange I. The results show that the 0.6g·L-1Orange I can be effectively degraded in pH4.0, hydrogen peroxide concentration 9 mmol·L-1, zero-valent iron concentration of 0.4g·L-1. The iron ion concentration and pH of each time period reaction mixture were determined by the UV-visible spectrophotometer and pH meter. The Orange I of each time period was scanned by the UV-visible spectrophotometer, and intermediate products were determined by LC-MS. It was presumed that the orange I first was dissociated to 4-hydroxy naphthalene azo benzene sulfonic acid, and then the chromophore was oxidative damaged leading to color fading of the reaction solution and generation of benzene sulfonic acid, nitrogen and 1, 4-naphthoquinone, then 1, 4-naphthoquinone was further oxidated to phthalic acid in the oxidative degradation reaction. 

Key Words: zero-valent iron; organic pollutant; oxidation; degradation rate; Orange I

 目录

第一章 前言 1

1.1 Fe0类Fenton技术 1

1.2 Fe0类Fenton技术的氧化机理 1

1.3 Fe0类Fenton技术的应用 2

1.4  试验目的及意义 2

1.4.1有机污染物的选取 3

1.4.2 研究的目的及意义 3

1.4.3 研究内容 3

第二章 实验部分 4

2.1 实验试剂与设备 4

2.1.1 实验试剂 4

2.1.2 实验设备 4

2.2 实验方法 5

2.3 测定内容及方法 5

2.3.1 金橙I降解率分析 5

2.3.2 金橙I降解动力学分析 5

2.3.3 铁离子浓度分析 6

2.3.4 pH值的测定 6

2.3.5 液质联用测定 6

2.3.6 数据处理 6

第三章 实验结果与分析 6 Fe0类Fenton技术氧化降解金橙I:http://www.youerw.com/huaxue/lunwen_63053.html

------分隔线----------------------------
推荐内容