摘要：对在常压下以油酸和乙二胺为原料在溶剂二甲苯中合成油酸酰胺实验的方法进行研究，通过正交试验得到了最佳的工艺条件为：反应时间2h，投料比1：1.4，反应温度120±5℃。利用红外光谱仪分析产物，并在环-块式摩擦磨损试验机和四球试验机上，测定了油酸酰胺添加到基础油后的摩擦磨损性能，对油酸酰胺添加量对这些性能的影响进行了考察。结果表明，含油酸酰胺1.5%（wt%）时，为最佳值。测定基础油、添加1.5%（wt%）油酸酰胺的基础油、添加T202的基础油三者的最大无卡咬负荷PB，结果表明添加T202后基础油的PB最大。最后测定油酸酰胺与T202复配后的摩擦化学性能以及两者的添加量对基础油的摩擦磨损性能的影响，结果表明，当添加1.5%（wt%）油酸酰胺和添加1%（wt%）T202复配时，润滑油的抗磨效果最佳。4568
关键词：正交试验；油酸酰胺；合成；T202；润滑油
TRIBOLOGICAL CHARACTERISTICS AND SYNTHESIS ON OLEIC AMIDE
ABSTRACT：Oleic amide was synthesized by oleic acid and ethylenediamide. The influences of some factors on the synthesis process were studied thorough orthogonal experiment. The optimal reaction conditions were chosen through orthogonal test that reaction time was 3 h, the molar ratio of oleic acid to ethylenediamide was 1：1.4, reaction temperature was 120±5℃. Its chemical structure was identified by IR spectra. Determine the friction and wear properties of the oleic amide added to base oil in the ring-block friction and wear testing machine and four-ball tester. Results showed that the best value of oleic amide is 1.5% (wt%). Determine the largest non-card bite load (PB) of 32# base oil, adding 1.5%(wt%) of oleic amide in the 32# base oil and adding the T202 base oil, the results showed that the PB of base oil after adding T202 is maximum. Finally, determine the chemical friction about the compound of oleic amide and T202 and the friction and wear performance impact of these two adding amount of base oil, the results show that when add 1.5%(wt%) of oleic amide and add 1%(wt%) of T202 compound, the anti-wear effect of lubricant is best.
KEY WORDS：orthogonal experiment；oleic amide；synthesis；T202；lubricant
目 录
1 绪论 1
1.1 润滑剂 1
1.2 润滑机理 2
1.3 润滑技术的进展 3
1.4 润滑油添加剂 4
1.5 润滑油添加剂的现状与发展趋势 7
1.6 油酸酰胺的物性数据及用途 8
1.7 酰胺的合成方法 8
1.8 油酸酰胺的提纯 10
1.9 摩擦学特性的测定 11
1.10 复配特性的研究 11
2实验试剂及仪器 13
2.1实验试剂 13
2.2 实验仪器 13
2.3 红外光谱 13
2.4 四球机 14
2.4.1 四球摩擦磨损试验机简介 14
2.4.2 四球摩擦磨损试验机的工作原理 14
2.4.3 四球摩擦磨损试验机的常规评定指标 14
3 实验内容 16
3.1 油酸酰胺的合成 16
3.2 红外光谱测试 17
3.3 摩擦学性能测定 17
4.实验结果与分析 18
4．1 油酸酰胺的合成 18
4.1.1 油酸酰胺合成实验结果 18
4.1.2 油酸酰胺合成实验结果分析 19
4.1.3 产物的红外谱图分析 20
4.1.4 小结 20
4.2 油酸酰胺及其与T202复配的摩擦学性能研究 21
4.2.1 油酸酰胺的磨斑直径试验 21 油酸酰胺的合成及摩擦学性能研究:http://www.youerw.com/huaxue/lunwen_1296.html